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alwaysOn:false, zoomWidth: 320, zoomHeight: 250 }); }); </script> <div id="b4p00gi" class="product_detail" id="pd1"> <h6 style="text-align: center;"><strong>? <span style="font-size: 24px;color: #333">煙臺某銅業(yè)有限公司廢氣處理</span></strong> <p class="smal-hide"><span>發(fā)布時(shí)間：2020-08-29 17:15</span> <span>點(diǎn)擊：<script src="/hyhb/count.php?view=yes&aid=778&mid=1" type='text/javascript' language="javascript"></script></span></p> </h6> <div id="7kqorx6" class="wznr"><div> <strong><img alt="" src="/uploads/allimg/191108/1-19110P92605Z9.jpg" style="width: 800px; height: 600px;" /><br /> 項目概況：</strong></div> <div> 該方案適用于處理煙臺銅業(yè)有限公司生產(chǎn)過(guò)程中產(chǎn)生廢氣，選用廢氣處理風(fēng)量為20000m³/h。</div> <div> 根據現場(chǎng)廢氣特點(diǎn)及相關(guān)數據和資料，借鑒相關(guān)工程實(shí)際設計和運行經(jīng)驗，本著(zhù)投資省、處理效果好、運行成本低的原則，編制了該設計方案，供企業(yè)和有關(guān)部門(mén)決策參考。</div> <div> 1.廢氣成分</div> <div> 2-丁烯醛</div> <div> 2-丁烯醛，是一種化學(xué)品，分子式為C4H6O，由乙醛在堿或陰離子交換樹(shù)脂催化作用下液相縮合生成丁醇醛，丁醇醛再在稀酸中加熱縮合脫水制得。有機合成原料，用于制取丁醛、丁醇、2-乙基己醇、山梨酸、3-甲氧基丁醛、3-甲氧基丁醇、丁烯酸、喹哪啶、順丁烯二酸酐及吡啶系產(chǎn)品。</div> <div> 有順式和反式兩種異構體。順式異色體不穩定。普通商品是反式異構體。無(wú)色透明易燃液體，有窒息性刺激氣味。與光或空氣接觸，變?yōu)榈S色液體，逐漸氧化成巴豆酸。其蒸氣對眼及呼吸道有毒，為極強的催淚劑。熔點(diǎn)-69℃，沸點(diǎn)102.2℃，相對密度0.8495（25/4℃），蒸氣相對密度2.41（空氣=1），折射率1.4384。閃點(diǎn)（開(kāi)杯）13℃。能與乙醇；乙醚；苯；甲苯；煤油和汽油等以任何比例互混，易溶于水，在水中的溶解度（重量%）：20℃為15.5℃；5℃為16.1。與水的共沸點(diǎn)為84℃，含丁烯醛75.7%（重量），純丁烯醛易樹(shù)脂化，能慢慢氧化成丁烯酸</div> <div> 與皮膚接觸有灼燒痛感，長(cháng)期吸入使人記憶力衰退，對黏膜組織有破壞作用。小鼠LC501.51mg/L。操作時(shí)應戴好口罩、手套等防護用品?？諝庵?高容許濃度0.5mg/m3。</div> <div> 非甲烷總烴</div> <div> 非甲烷總烴只要包括烷烴、烯烴、芳香烴和含氧烴等組分。烴類(lèi)物質(zhì)在通常條件下，除甲烷基化為氣體外多以液態(tài)或固態(tài)存在，并依據其分子大小結構形式外的差別具有不同的蒸汽壓，因而作為大氣污染物質(zhì)非甲烷總烴，實(shí)際上是指具有C2-C12的烴類(lèi)物質(zhì)。</div> <div> 大氣中的NMHC超過(guò)一定濃度，除直接對人體健康有害外，在一定條件下經(jīng)日光照射還能產(chǎn)生光化學(xué)煙霧，對環(huán)境和人類(lèi)造成危害。</div> <div> <strong>方案綜述</strong></div> <div> 煙臺銅業(yè)有限公司產(chǎn)生的廢氣主要為電爐加熱過(guò)程以及沖壓床沖壓過(guò)程中由于要使用色拉油，色拉油高溫加熱后產(chǎn)生的廢氣，由于電爐產(chǎn)生的廢氣溫度較高為80攝氏度，因此需要降溫，將沖壓床產(chǎn)生的廢氣與電爐產(chǎn)生的廢氣混合后處理廢氣的同時(shí)起到降溫的作用，電爐產(chǎn)生的廢氣風(fēng)量為6782m³/h,降溫需要補充風(fēng)量為10173m³/h,總計風(fēng)量為：16955m³/h,設計按照20000m³/h進(jìn)行設計。將兩部分廢氣統一收集后送入UV光氧催化設備進(jìn)行分解處理，經(jīng)過(guò)玻璃纖過(guò)濾掉5um以上的顆粒，再經(jīng)過(guò)高效過(guò)濾袋過(guò)濾掉0.5um-5um的顆粒，利用催化劑及高能高臭氧UV紫外線(xiàn)光束分解空氣中的氧分子產(chǎn)生游離氧，即活性氧，因游離氧所攜正負電子不平衡所以需與氧分子結合，進(jìn)而產(chǎn)生臭氧，再通過(guò)臭氧進(jìn)行氧化反應，徹底達到凈化及殺滅細菌的目的，再經(jīng)過(guò)高效蜂窩活性炭吸附徹底除去廢氣中的有害物質(zhì)，*后通過(guò)后端風(fēng)機抽風(fēng)高空達標排放。</div> <div> <strong>主要設備</strong></div> <div> 主處理系統（UV光氧催化設備）</div> <div> 特制UV紫外線(xiàn)燈：利用特制的高能高臭氧UV紫外線(xiàn)光束照射廢氣，裂解工業(yè)廢氣如：氨、三甲胺、硫化氫、甲硫氫、甲硫醇、甲硫醚、乙酸丁酯、乙酸乙酯、二甲二硫、二硫化碳和苯乙烯，硫化物H2S、VOC類(lèi)，苯、甲苯、二甲苯的分子鏈結構，使有機或無(wú)機高分子惡臭化合物分子鏈，在高能紫外線(xiàn)光束照射下，降解轉變成低分子化合物，如CO2、H2O等。利用高能高臭氧UV紫外線(xiàn)光束分解空氣中的氧分子產(chǎn)生游離氧，即活性氧，因游離氧所攜正負電子不平衡所以需與氧分子結合，進(jìn)而產(chǎn)生臭氧。 UV＋O2→O-+O＊(活性氧)O+O2→O3(臭氧)，眾所周知臭氧對有機物具有極強的氧化作用，對工業(yè)廢氣及其它刺激性異味有立竿見(jiàn)影的清除效果。工業(yè)廢氣利用排風(fēng)設備輸入到本凈化設備后，凈化設備運用高能UV紫外線(xiàn)光束及臭氧對工業(yè)廢氣進(jìn)行協(xié)同分解氧化反應，使工業(yè)廢氣物質(zhì)其降解轉化成低分子化合物、水和二氧化碳，再通過(guò)排風(fēng)管道排出室外。利用高能-C光束裂解工業(yè)廢氣中細菌的分子鍵，破壞細菌的核酸（DNA），再通過(guò)臭氧進(jìn)行氧化反應，徹底達到凈化及殺滅細菌的目的．從凈化空氣效率考慮，我們選擇了-C波段紫外線(xiàn)和臭氧發(fā)結合電暈電流較高化裝置采用脈沖電暈放吸附技術(shù)相結合的原理對有害氣體進(jìn)行消除，其中-C波段紫外線(xiàn)主要用來(lái)去除硫化氫、氨、苯、甲苯、二甲苯、甲醛、乙酸乙酯、乙烷、丙酮、尿烷、樹(shù)脂等氣體的分解和裂變，使有機物變?yōu)闊o(wú)機化合物。</div> <div> 特制高效催化劑：根據不同的廢氣成分配置27種以上相對應的惰性催化劑，催化劑采用蜂窩狀金屬網(wǎng)孔作為載體，全方位與光源接觸，惰性催化劑在338納米光源以下發(fā)生催化反應，放大10-30倍光源效果，使其與廢氣進(jìn)行充分反應，縮短廢氣與光源接觸時(shí)間，從而提高廢氣凈化效率，催化劑還具有類(lèi)似于植物光合作用，對廢氣進(jìn)行凈化效果。 </div> <div> （3）活性炭吸附箱</div> <div> 采用煤基耐水蜂窩活性炭（100×100×100mm，100孔/平方英寸）作為吸附劑，蜂窩活性炭經(jīng)過(guò)耐水處理和二次燒制，具有體積密度小、比表面積大、吸附效率高、機械強度高、耐水、耐強酸、強堿的特性。蜂窩活性炭的多孔結構風(fēng)阻系統小，有優(yōu)良的氣體動(dòng)力學(xué)性能。同時(shí)蜂窩狀活性灰吸附、脫附性能良好，可以使吸附體積縮小，降低設備造價(jià)及運行成本。</div> <div> 床層阻力只有顆粒狀活性炭的1/10左右，實(shí)測阻力不大于70mmH2O（600 Pa），與顆?；钚蕴肯啾葍?yōu)勢明顯，適合應用于大風(fēng)量廢氣處理；無(wú)需采用大功率的高壓風(fēng)機，運行電耗明顯降低，且吸附箱體積及占地面積小。</div> <div> </div> <div> </div> <div> 蜂窩活性炭吸附設備運行阻損低：在同等條件下，蜂窩活性炭的運行阻力損失是低于其他吸附劑（如碳纖維和顆粒碳），故裝置的能耗相對較低。</div> <div> 抗堵塞能力強：由于蜂窩活性炭特有的結構，對漆霧、粉塵等耐久性較強，更適合于噴漆廢氣治理的場(chǎng)合。</div> <div> 設備箱體采用Q235鍍鋅材料，保證材料表面防銹效果良好，外表面溫度小于50℃，高溫部分設警示標志。箱體采用模塊化設計，活性炭獨立安裝，方便快捷，維護方便。</div> <div> （4）風(fēng)機</div> <div> 廢氣風(fēng)機采用防火花結構設計（吸入口鑲銅片），強化系統在易燃易爆環(huán)境中設備的安全性。</div> <div> 廢氣風(fēng)機采用變頻控制，系統在運行過(guò)程中，可隨著(zhù)風(fēng)量的變化，通過(guò)風(fēng)機前管道壓力變化控制風(fēng)機頻率，改變風(fēng)機風(fēng)量，節能降耗，并確保用戶(hù)范圍生產(chǎn)線(xiàn)的穩定。<br /> <div> 售后服務(wù)</div> <div> 提供24h服務(wù)電話(huà)，在接到客戶(hù)技術(shù)服務(wù)請求的通知后 24小時(shí)內，到達客戶(hù)現場(chǎng)；</div> <div> 提供安裝與調試服務(wù)，并提供緊急搶修服務(wù)；</div> <div> 在質(zhì)保期內對所供設備實(shí)行免費三包。</div> <div> 為用戶(hù)提供免費技術(shù)服務(wù)，提供遠程數據評估。</div> <div> 為客戶(hù)操作人員提供全面的技術(shù)培訓。</div> <div> 為客戶(hù)操作人員提供PLC軟件的升級服務(wù)。</div> <div> 為客戶(hù)提供定期隨訪(fǎng)服務(wù)。</div> <div> </div> </div> <br /> </div> <p 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