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href="http://ujianfei.com/static/css/jquery.jqzoom.css" /> <script type="text/javascript" src="http://ujianfei.com/static/js/jquery.jqzoom-core.js"></script> <script type="text/javascript"> $(document).ready(function() { $('.jqzoom').jqzoom({ zoomType: 'standard', lens:true, preloadImages: false, alwaysOn:false, zoomWidth: 320, zoomHeight: 250 }); }); </script> <div id="ggo0cua" class="product_detail" id="pd1"> <h6 style="text-align: center;"><strong>? <span style="font-size: 24px;color: #333">環(huán)亞環(huán)保告訴您行業(yè)中常見(jiàn)的各類(lèi)重金屬廢氣處理方法</span></strong> <p class="smal-hide"><span>發(fā)布時(shí)間：2019-11-21 09:18</span> <span>點(diǎn)擊：<script src="/hyhb/count.php?view=yes&aid=1221&mid=1" type='text/javascript' language="javascript"></script></span></p> </h6> <div id="kys2eyq" class="wznr"><div> 重金屬廢氣的基本處理方法包括：過(guò)濾法、吸收法、吸附法、冷凝法和燃燒法。</div> <div> 汞及其化合物廢氣處理</div> <div> 一般處理方法：吸收法、吸附法、冷凝法和燃燒法。</div> <div> 冷凝法：適合凈化回收高濃度的汞蒸汽，常作為吸收法和吸附法凈化汞蒸汽的前處理。</div> <div> 吸收法：</div> <div> 高錳酸鉀溶液吸收法-適用于儀表電器廠(chǎng)的含汞蒸汽;</div> <div> 次氯酸鈉溶液吸收法-適用于處理水銀法氯堿廠(chǎng)含汞氫氣;</div> <div> 硫酸-軟錳礦吸收法-適用于處理煉汞尾氣以及含汞蒸汽;</div> <div> 氨液吸收法適用于氯化汞生產(chǎn)廢氣的凈化;</div> <div> 氯化法處理汞蒸汽。</div> <div> 吸附法：</div> <div> 充氯活性炭吸附法適用于含汞廢氣處理;</div> <div> 活性炭吸附法適用于氯乙烯合成氣中氯化汞的凈化;</div> <div> 消化吸附法適用于雷汞的處理。</div> <div> 燃燒法</div> <div> 適用于燃煤電廠(chǎng)含汞煙氣的處理。采用循環(huán)流化床燃煤鍋爐，燃燒過(guò)程中投加石灰石，煙氣采用電除塵或袋除塵凈化。</div> <div> 鉛及其化合物廢氣處理</div> <div> 鉛及其化合物廢氣適合用吸收法處理。</div> <div> 酸液吸收法適用于凈化氧化鉛和蓄電池生產(chǎn)中產(chǎn)生的含鉛煙氣，也可用于凈化熔化鉛時(shí)所產(chǎn)生的含鉛煙氣。</div> <div> 建議采取二級凈化工藝：第*級采用袋濾器除去較大顆粒;第二級采用化學(xué)吸收。吸收劑一般采用醋酸。</div> <div> 堿液吸收法適用于凈化化鉛鍋、冶煉爐產(chǎn)生的含鉛煙氣。吸收劑一般采用NaOH溶液。</div> <div> 砷、鉻、鎘及其化合物廢氣處理</div> <div> 砷、鉻、鎘及其化合物廢氣通常采用吸收法和過(guò)濾法處理。</div> <div> 含砷煙氣應采用冷凝(200度以下)-除塵(袋除塵器)-石灰乳吸收法處理工藝</div> <div> 鉻、鎘及其化合物廢氣宜采用袋式除塵器過(guò)濾處理(風(fēng)速小于1m/min)</div> <div> 幾種重金屬危害</div> <div> 重金屬廢氣主要來(lái)源于有色冶煉、電力、化工、機械加工等行業(yè)中產(chǎn)生的含汞、含鉛、含砷等及其化合物廢氣，有色冶煉行業(yè)中重金屬通過(guò)廢氣的排放量已經(jīng)超過(guò)廢水的重金屬排放量，嚴重威脅環(huán)境與人類(lèi)的健康。</div> <div> 銅(Cu)：金屬銅的毒性很小，但銅的化合物可引起中毒。當人體內的銅超過(guò)人體需要量的100~150倍時(shí)可導致壞死性肝炎、溶血性貧血等癥狀。臨床研究發(fā)現很多癌癥患者血清銅明顯增多，血清銅蘭蛋白增加。</div> <div> 對用硫酸銅為殺蟲(chóng)劑噴灑葡萄的植園工人進(jìn)行詳細抽樣調查發(fā)現這些人普遍存在著(zhù)肝損傷。而誤服較大劑量的銅制劑會(huì )立即引起流涎、惡心、嘔吐、溶血、黃疽、腎功能衰竭和中樞神經(jīng)系統抑制等中毒癥狀。</div> <div> 鉛(Pb)：鉛可以通過(guò)呼吸道和消化道進(jìn)入人體，長(cháng)期接觸濃度在50mg/L以上的鉛，便會(huì )中毒。鉛對全身各器官均有毒害作用，但以神經(jīng)系統、血液和心血管系統為甚。慢性中毒*常見(jiàn)的癥狀為貧血、腹絞痛和鉛中毒性肝炎。在神經(jīng)系統方面的癥狀為植物神經(jīng)衰弱和多發(fā)性神經(jīng)炎，表現為腦下垂體鉛中毒神經(jīng)麻痹，嚴重者可發(fā)生鉛性腦病。</div> <div> 鋅(Zn)：有實(shí)驗表明體內高鋅會(huì )導致血中高密度脂蛋白下降而促發(fā)動(dòng)脈粥樣硬化，鋅過(guò)高還利于癌腫的發(fā)生。英國北威爾士等地土壤中含鋅高，其胃癌和消化道部位癌腫發(fā)生率也高。</div> <div> 工業(yè)鋅中毒可使各種類(lèi)型的癌腫發(fā)生率升高，長(cháng)期低劑量或短期大劑量暴露于鋅中，可致急、慢性鋅中毒。</div> <div> 鐵(Fe)：研究人員早己發(fā)現含鐵血紅素沉著(zhù)癥是鐵在體內過(guò)多并沉著(zhù)于內臟引起的。英、美等國家曾報道鐵礦工人中肺癌發(fā)生率高，且比一般人肺癌死亡率高70%。鐵可促使腫瘤細胞迅速生長(cháng)。</div> <div> 鎳(Ni)：鎳的毒性雖然較小，但有積蓄作用且是致癌物質(zhì)。鎳極易在腎、脾、肝中蓄積。經(jīng)常接觸鎳鹽，皮膚會(huì )產(chǎn)生濕疹及皮炎等癥狀。</div> <div> 鉻(Cr)：鉻化合物中以六價(jià)鉻毒性*強，三價(jià)鉻次之，二價(jià)鉻和鉻本身的毒性很小。鉻化合物可通過(guò)消化道、呼吸道、皮膚和粘膜進(jìn)入人體。經(jīng)消化道進(jìn)入人體可引起惡心、嘔吐、腹痛，也能引起潰瘍病;經(jīng)呼吸道進(jìn)入人體時(shí)，首先侵害上呼吸道，引起鼻炎、咽炎、支氣管炎等。</div> <div> 汞及其化合物廢氣處理<br /> <img alt="廢氣處理設備" src="/uploads/allimg/191121/1-191121094Q12H.jpg" style="width: 680px; height: 509px;" /></div> <div> 汞及其化合物廢氣一般處理方法是：吸收法，吸附法，冷凝法和燃燒法。</div> <div> 冷凝法宜用于凈化回收高濃度的汞蒸氣，可采取常壓和加壓兩種方式，常作為吸收法和吸附法凈化汞蒸氣的前處理。</div> <div> 針對不同的工業(yè)生產(chǎn)工藝，較為成熟的吸收法處理工藝有：</div> <div> a)高錳酸鉀溶液吸收法適用于處理儀表電器廠(chǎng)的含汞蒸氣，循環(huán)吸收液宜為0.3%～0.6% KMnO4溶液，KMnO4利用率較低，應考慮吸收液的及時(shí)補充;</div> <div> b)次氯酸鈉溶液吸收法適用于處理水銀法氯堿廠(chǎng)含汞氫氣，吸收液宜為NaCl與NaClO的混合水溶液，此吸收液來(lái)源廣，但此工藝流程復雜，操作條件不易控制;</div> <div> c)硫酸-軟錳礦吸收法適用于處理煉汞尾氣以及含汞蒸氣，吸收液為硫酸-軟錳礦的懸濁液;</div> <div> d)氯化法處理汞蒸氣：煙氣進(jìn)入脫汞塔，在塔內與噴淋的HgCl2溶液逆流洗滌，煙氣中的汞蒸氣被HgCl2溶液氧化生成Hg2Cl2沉淀，從而將汞去除。Hg2Cl2沉淀劇毒，生產(chǎn)過(guò)程中需加強管理和操作。</div> <div> 充氯活性炭吸附法宜用于含汞廢氣處理?；钚蕴繉有桀A先充氯，含汞蒸氣需預除塵，汞與活性炭表面的Cl2反應生成HgCl2，達到除汞目的。</div> <div> 燃燒法宜用于燃煤電廠(chǎng)含汞煙氣的處理。采用循環(huán)流化床燃煤鍋爐，燃燒過(guò)程中投加石灰石，煙氣采用電除塵器或袋除塵器凈化。</div> <div> 廢氣中重點(diǎn)控制的汞的化合物包括氯化汞和雷汞。</div> <div> a)活性炭吸附法宜用于氯乙烯合成氣中氯化汞的凈化;</div> <div> b)氨液吸收法宜用于氯化汞生產(chǎn)廢氣的凈化;</div> <div> c)消化吸附法宜用于雷汞的處理。</div> <div> 鉛及其化合物廢氣處理</div> <div> 鉛及其化合物廢氣宜用吸收法處理。</div> <div> 酸液吸收法適用于凈化氧化鉛和蓄電池生產(chǎn)中產(chǎn)生的含鉛煙氣，也可用于凈化熔化鉛時(shí)所產(chǎn)生的含鉛煙氣。宜采用二級凈化工藝：第*級用袋濾器除去較大顆粒;第二級用化學(xué)吸收。吸收劑(醋酸)的腐蝕性強，應選用防腐蝕性能高的設備;</div> <div> 堿液吸收法適用于凈化化鉛鍋、冶煉爐產(chǎn)生的含鉛煙氣。含鉛煙氣進(jìn)入沖擊式凈化器進(jìn)行除塵及吸收。吸收劑NaOH溶液腐蝕性強，應選用防腐蝕性能高的設備。</div> <div> 砷、鎘、鉻及其化合物廢氣處理</div> <div> 砷、鎘、鉻及其化合物廢氣通常采用吸收法和過(guò)濾法處理。</div> <div> 含砷煙氣宜采用冷凝-除塵-石灰乳吸收法處理工藝。含砷煙氣經(jīng)冷卻至200℃以下，蒸汽狀態(tài)的氧化砷迅速冷凝為微粒，經(jīng)袋除塵器凈化后，尾氣進(jìn)入噴霧塔，用石灰乳洗滌，凈化后，尾氣除霧，經(jīng)引風(fēng)機排空。含砷煙氣亦可在塑料板(或管)制成的吸收器內裝入強酸性飽和高錳酸鉀溶液，進(jìn)行多級串聯(lián)鼓泡吸收。</div> <div> 鎘、鉻及其化合物廢氣宜采用袋式除塵器在風(fēng)速小于1 m/min時(shí)過(guò)濾處理。煙氣溫度較高需要采取保溫措施。</div> </div> <p 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