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href="http://ujianfei.com/static/css/jquery.jqzoom.css" /> <script type="text/javascript" src="http://ujianfei.com/static/js/jquery.jqzoom-core.js"></script> <script type="text/javascript"> $(document).ready(function() { $('.jqzoom').jqzoom({ zoomType: 'standard', lens:true, preloadImages: false, alwaysOn:false, zoomWidth: 320, zoomHeight: 250 }); }); </script> <div id="arcyj2q" class="product_detail" id="pd1"> <h6 style="text-align: center;"><strong>? <span style="font-size: 24px;color: #333">催化氧化技術(shù)簡(jiǎn)介</span></strong> <p class="smal-hide"><span>發(fā)布時(shí)間：2020-10-09 13:29</span> <span>點(diǎn)擊：<script src="/hyhb/count.php?view=yes&aid=2164&mid=1" type='text/javascript' language="javascript"></script></span></p> </h6> <div id="3ztg22d" class="wznr"><div> 催化氧化法始于20世紀40年代，主要用于工業(yè)惡臭廢氣處理和裝置的能量回收。由于催化氧化技術(shù)具有高效、節能、環(huán)保、產(chǎn)物易于控制等優(yōu)點(diǎn)，目前已成為凈化可燃性含碳氫化合物和惡臭氣體的有效手段。</div> <div> 催化氧化技術(shù)已成功應用于化工噴涂、漆包線(xiàn)、印刷、煉焦、絕緣材料等眾多行業(yè)的揮發(fā)性有機污染物廢氣凈化。催化氧化技術(shù)是典型的氣-固相催化過(guò)程，反應中揮發(fā)性有機廢氣在催化劑的作用下發(fā)生完全氧化反應。催化劑的作用是降低反應的活化能，同時(shí)使反應物分子富集于催化劑表面，提高反應速率，借助催化劑可以使有機廢氣在較低的起燃溫度下發(fā)生無(wú)火焰燃燒，并氧化為CO2和H2O，同時(shí)放出大量的熱。催化氧化法的凈化效率通常在95%以上，其主要工藝流程如圖2-1所示。<br /> <img alt="" src="/uploads/allimg/201009/1-201009133542138.jpg" style="width: 750px; height: 363px;" /></div> <div> 當有機廢氣量較大時(shí)，工程上一般將換熱器、燃燒室和催化床分別設計成獨立設備（分建式），相互間用管路連接；當有機廢氣量較小時(shí)，預熱器、燃燒室和催化床安裝在同一個(gè)設備中（組合式）。</div> <div> <img alt="" src="/uploads/allimg/201009/1-2010091336104C.png" style="width: 750px; height: 413px;" /></div> <div> 待處理廢氣一般借助催化燃燒后的凈化氣預熱，當有機廢氣溫度較低，且經(jīng)過(guò)預熱后仍不能達到催化燃燒溫度時(shí)，多數情況下是利用輔助燃料燃燒產(chǎn)生高溫燃氣與廢氣均勻混合升溫，大部分碳氫化合物可在500℃以?xún)韧ㄟ^(guò)催化劑床層迅速氧化［式（2-1）］。催化氧化的實(shí)質(zhì)是活性氧參與的劇烈氧化反應，催化劑活性組分將空氣氧活化，當與反應物分子接觸時(shí)發(fā)生能量傳遞，反應物分子被活化，從而加速氧化反應的進(jìn)行。根據不同氧化階段的氧化溫度不同，催化氧化大致可以分為以下三個(gè)階段：</div> <div> ①低溫階段，反應為內表面反應動(dòng)力學(xué)控制；</div> <div> ②中間階段，反應速率受到擴散過(guò)程控制；</div> <div> ③高溫階段，催化活性對整個(gè)反應過(guò)程的控制變得尤為明顯。</div> <div> <img alt="" src="/uploads/allimg/201009/1-201009133629127.jpg" style="width: 732px; height: 75px;" /></div> <div> 無(wú)火焰催化氧化技術(shù)是VOCs治理行業(yè)中應用*為廣泛的方法之一，其具有以下優(yōu)點(diǎn)：</div> <div> ①起燃溫度低，能量消耗少。催化氧化起燃溫度通常為250～500℃，能耗較少。由于反應溫度降低，允許使用標準材料來(lái)代替昂貴的特殊材料，大大降低了設備費用和操作成本。</div> <div> ②應用范圍廣。催化氧化適用于濃度范圍廣、成分復雜的各種有機廢氣處理。目前催化氧化技術(shù)已成功地應用于金屬漆包線(xiàn)、絕緣材料、印刷等生產(chǎn)過(guò)程中排放的有機廢氣處理，由于廢氣溫度和有機物濃度較高，催化氧化能實(shí)現自身熱平衡和部分熱量再利用，因此具有較好的經(jīng)濟效益。</div> <div> ③設備簡(jiǎn)單，易升級改造。由于催化反應在催化劑表面進(jìn)行，提高了體積燃燒速率，燃燒鍋爐可以小型化。當前，大部分燃燒設備采用的都是非催化燃燒，將現有的均相燃燒改革為催化燃燒只要將現有設備進(jìn)行簡(jiǎn)單升級改造即可實(shí)現，滿(mǎn)足達標排放的要求。</div> <div> ④凈化效率高，二次污染少。用深度催化氧化法處理有機廢氣的凈化效率一般都在95%以上，且*終產(chǎn)物為無(wú)污染的CO2和H2O，因此較少出現二次污染問(wèn)題，且氧化氣氛緩和，運轉費用低，操作管理方便。此外，由于反應溫度低，深度催化氧化能很好地控制熱力型NOx的生成。</div> </div> <p id="cztz">版權聲明：本網(wǎng)注明來(lái)源為“環(huán)亞環(huán)?！钡奈淖?、圖片內容，版權均屬本站所有，如若轉載，請注明本文出處：http://ujianfei.com 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